Holders The Champions League round of 16 will see Manchester City play FC Copenhagen and Spanish powerhouse Barcelona play Napoli.
Several noteworthy matches were exhibited at Monday’s draw in Nyon.
Copenhagen, who twice faced Manchester United, a rival of City, in the competition’s group stage, will go back to Manchester to take on Pep Guardiola’s team.
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The champions, who have won 20 straight European football games and all six of their group-stage games, will present a formidable challenge to the Danish squad.
After being matched up against each other, one of the Serie A or La Liga champions, Napoli or Barcelona, will not advance.
Three-time runners-up Atletico Madrid will play last year’s finalists Inter Milan in another match between Italian and Spanish teams.
record 14 victories Real Madrid will play RB Leipzig of Germany, while Arsenal, the top team in the English Premier League, will face Porto in a challenging match.
Arsenal had not defeated the two-time champions away from home, despite winning all three of their prior Champions League home games against Porto by a combined score of 11-0.
Borussia Dortmund will meet Dutch leaders PSV Eindhoven, while Harry Kane-led Bayern Munich takes on Lazio of Italy. Borussia Dortmund will also make their reunion with former manager Peter Bosz.
Arsenal had not defeated the two-time champions away from home, despite winning all three of their prior Champions League home games against Porto by a combined score of 11-0.
Borussia Dortmund will meet Dutch leaders PSV Eindhoven, while Harry Kane-led Bayern Munich takes on Lazio of Italy. Borussia Dortmund will also make their reunion with former manager Peter Bosz.
As they pursue their first-ever European Cup, Real Sociedad of Spain will take on French champions Paris St. Germain, who just made it through a challenging group stage.
The first legs take place on February 13 and 14 or February 20 and 21 next year and the second on March 5 and 6 or 12 and 13.
UEFA CHAMPIONS LEAGUE DRAW IN FULL
Arsenal v FC Porto
Barcelona v Napoli
Real Sociedad v Paris St Germain
Atletico Madrid v Inter Milan
Borussia Dortmund v PSV Eindhoven
Bayern Munich v Lazio
Manchester City v FC Copenhagen
Real Madrid v RB Leipzig